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Solutions for Chemistry, Class 9, ICSE
State what is meant by the term 'atmospheric pollution'. Name four gaseous atmospheric pollutants.
Answer
Atmospheric pollution means conditions of air made unclean due to introduction of foreign elements from (i) Natural sources (ii) Man made sources to the air so as to cause adverse effects on living organisms on earth.
Four gaseous pollutants are:
Explain the term 'acid rain'. State the two forms of deposition of acid rain with suitable examples of each form of deposition.
Answer
The term 'acid rain' refers to the various ways in which the acids formed in the atmosphere condense and fall on the earth.
The two forms of depositions of acid rain are:
State the natural and man-made sources of the two pollutants responsible for acid rain.
Answer
Burning of fossil fuels is an important source of the pollutant – 'oxides of sulphur' responsible for acid rain. State what are 'fossil fuels'. Name the principal fossil fuels. State why sulphur dioxide is emitted on burning a fossil fuel. Give a balanced equation for the same.
Answer
Fuels that are derived from organic remains of plants and animals are called fossil fuels.
Principal fossil fuels — coal, petroleum [oil], natural gas.
Sulphur impurities are present in fossil fuels which produce sulphur dioxide when the fossil fuel is burnt. Balanced chemical equation for the same is given below:
S + O2 ⟶ SO2
During metallurgy – smelting plants produce sulphur dioxide, when metallic sulphides are roasted in air. Give a balanced equation for the same.
Answer
Balanced equation representing the emission of sulphur dioxide when metallic sulphides are roasted in air is given below:
2ZnS + 3O2 ⟶ 2ZnO + 2SO2
State why high temperatures in internal combustion engines release pollutant – oxides of nitrogen.
Answer
In internal combustion engines, combustion of fossil fuel occurs with an oxidiser (air). The air drawn from the atmosphere contains about 80% nitrogen. The nitrogen combines with oxygen at high temperature producing oxides of nitrogen.
N2 + O2 ⟶ 2NO [at high temp.]
Thus, exhaust gases of all internal combustion engines release oxides of nitrogen.
State why natural rain water produced in an unpolluted atmosphere is slightly acidic. Give a balanced equation of the same.
Answer
Natural rain water produced in an unpolluted atmosphere is slightly acidic as CO2 present in traces in unpolluted air dissolves in rain water forming weak carbonic acid [H2CO3].
H2O + CO2 ⟶ H2CO3 [carbonic acid]
Give balanced equations for the formation of sulphuric acid in acid rain, when a fossil fuel is burnt in an electric power station.
Answer
Thus, the acidity of rain is due to reaction of oxides of sulphur with water vapour forming dilute acids.
Starting from nitrogen in air, enlist the reactions with the help of balanced equations, which result in the conversion of nitrogen in an internal combustion engine, to the acids formed which are responsible for acid rain.
Answer
Thus the acidity in the rain is due to reaction of oxides of nitrogen with water vapour forming dilute acids.
Explain the basic function of a catalytic converter in an internal combustion engine.
Answer
The basic function of a catalytic converter in internal combustion engine is to help reduce pollution.
The reduction catalyst [Pt/Pd] in a converter separates the nitrogen atom from NO and NO2 molecules freeing oxygen in the form of O2 molecule.
2NO ⟶ N2 + O2
2NO2 ⟶ N2 + 2O2
Thus, the oxides of nitrogen which are pollutants are converted to free nitrogen.
State why acid rain causes 'nutrient leaching' when it falls on the earth.
Answer
The hydrogen ions which are added to the soil - when acid rain falls on the earth - interact chemically with existing soil minerals.
H2SO4 ⇌ 2H1+ + SO42-
Minerals like potassium and calcium interact with the H1+ ions and are displaced from the soil, thus the soil is deprived of nutrients causing nutrient leaching.
Give reasons why acid rain affects marine organisms.
Answer
Toxic metals like - mercury, lead, zinc present in the soil, get leached by acid rain thus toxicity enters rivers and streams and destroys aquatic plants and animals.
State the impact of acid rain on the environment, other than soil chemistry and water bodies.
Answer
Acid rain affects :
Enumerate the ways by which acid rain can be controlled to prevent it's adverse effects on the environment.
Answer
Ways to control acid rain:
State what are 'green house gases' and name the major green house gases.
Answer
Green house gases are those gases that contribute effectively in retaining heat in the atmosphere.
Major green house gases are carbon dioxide, methane, water vapours, oxides of nitrogen and chlorofluorocarbons.
State what is meant by the term – 'green house effect' and state it's consequence.
Answer
Green house effect is the warming up of the earth's surface, due to concentration or blanketing effect of the green house gases.
The green house effect results in rise of atmospheric temperature which is not confined to one region but also has a global impact and is termed as global warming.
Explain how global warming takes place in the presence of green house gases. Give a reason why the surface temperature of earth is maintained in absence of green house gases.
Answer
The green house effect results in rise of atmospheric temperature which is not confined to one region but also has a global impact and is termed as global warming.
In absence of green house gases the surface temperature on earth is maintained since -
Thus, a balance is maintained between the heat energy absorbed by the earth and radiated from the earth.
Give balanced equations for formation of carbon dioxide – a major green house gas, during combustion of fossil fuels.
Answer
Balanced equations for formation of carbon dioxide during combustion of fossil fuels are given below:
State two natural and two man-made sources of the green house gas – methane.
Answer
Two natural sources of Methane are:
Two man-made sources of Methane are:
'Oxides of nitrogen namely nitrous oxide, are released into the atmosphere from varied sources'. Explain the statement with relevant sources.
Answer
Oxides of nitrogen (namely nitrous oxide), are released into the atmosphere from various natural and man-made sources. The natural sources are:
The man-made sources are:
State the impact of green house gases on geographic, climatic and agricultural conditions.
Answer
Impact of green house gases on:
Give the options for reducing green house gases by use of fuels better than fossil fuels.
Answer
The following fuels can be used which are better than fossil fuels as they release less green house gases:
State three renewable energy sources which cause less or no pollution.
Answer
Renewable sources of energy are:
Explain how promoting 'afforestation' and checking 'deforestation' reduces the release of green house gases.
Answer
Promoting afforestation means to induce more growth of plantation and forests. This helps to absorb green house gas - carbon dioxide during photosynthesis.
Checking deforestation means to reduce burning of forests and biomass. This helps to control the emission of green house gases.
What is an ozone layer. State the distribution of the ozone layer in the stratosphere.
Answer
Ozone layer is the layer in the earth's atmosphere which contains relatively high concentration of ozone. It absorbs 97-99% of the sun's high frequency U.V. light which is damaging to life on earth. Thus, Ozone layer protects life on earth from harmful solar rays.
Distribution of the Ozone Layer in the Stratosphere:
Give balanced equations for formation of ozone molecules from oxygen molecules. What type of reaction takes place, during the formation.
Answer
Highly energetic ultraviolet radiations from the sun breaks the oxygen molecule [O2] into two oxygen atoms. This reaction is photodissociation or photolysis.
Highly reactive oxygen atom [O] can then react with oxygen molecule [O2] to form ozone [O3]
O2 [O] + [O]
O2 + [O] ⟶ O3 [ozone]
How is the 'ozone oxygen cycle' maintained in the stratosphere and state what disturbs the balance, resulting in ozone depletion or destruction, Give balanced equation for the same.
Answer
Ozone is formed in the stratosphere — Highly energetic ultraviolet radiations from the sun breaks the oxygen molecule [O2] into two atoms. This reaction is photodissociation or photolysis.
Highly reactive oxygen atom [O] can then react with oxygen molecule [O2] to form ozone [O3]
O2 [O] + [O]
O2 + [O] ⟶ O3 [ozone]
Ozone is also broken down in the stratosphere — In unpolluted air containing minimal chemical compounds, unstable ozone molecule, in presence of solar radiations may split into molecular oxygen [O2] and an atom of atomic oxygen [O].
The atomic oxygen then combines with another ozone molecule to form two molecules of molecular oxygen.
O3 O2 + [O]
O3 + [O] ⟶ 2O2
Thus a continuing process called 'ozone oxygen cycle' is maintained between the amount of ozone [O3] being produced and being destroyed. As a result, the total concentration of ozone remains almost the same.
The balance is disturbed by release of chemicals — such as chlorofluorocarbons containing atomic chlorine and bromine and other free radicals which breaks the ozone molecule causing ozone depletion.
Enumerate the damage to humans, animals and plants caused due to ozone depletion.
Answer
Damage to Humans and Animals:
Damage to plants:
Name the chemicals responsible for destruction of the ozone layer. State the main chemical from these chemicals, which is responsible for more than 80% ozone depletion. State the man-made applications which make use of that chemical.
Answer
Chemicals responsible for ozone depletion are :
Out of the above chemicals, Chlorofluorocarbons (CFCs) is the main chemical responsible for more than 80% ozone depletion.
Man-made applications making use of Chlorofluorocarbons (CFCs) are:
State the role of chlorofluorocarbons in ozone destruction or depletion [no equations required].
Answer
Ozone is broken down by chlorofluorocarbons in the following way:
Enumerate methods of protecting the ozone layer and preventing it's depletion.
Answer
Ozone layer can be protected by :
Name any two natural sources of atmospheric pollution.
Answer
Two natural sources of atmospheric pollution are:
Name any two gases which are responsible for the formation of acid rain.
Answer
Explain the term 'global warming'.
Answer
The warming up of the earth's surface, due to concentration or blanketing effect of the green house gases (Green house effect) results in the rise of atmospheric temperatures. This is not confined to one region but has a global impact and is termed as global warming.
State two effects of ozone depletion.
Answer
What is meant by the term 'acid rain'. Give any two impacts of acid rain.
Answer
The term 'acid rain' refers to the various ways in which the acids formed in the atmosphere - condense and fall on the earth resulting in acid rain.
Impacts of acid rain :
State two ways by which global warming can be reduced.
Answer
Global warming can be reduced by reducing the emission of green house gases by :
State an advantage of using solar energy.
Answer
Solar energy is a renewable source of energy that does not cause pollution and helps in reducing global warming as it does not emit greenhouse gases.
Explain the methods of preventing acid rain.
Answer
Method of preventing acid rain are:
State an advantage of CNG [compressed natural gas].
Answer
CNG is an alternative to petrol and diesel since it causes minimum pollution. It does not contain lead and lowers maintenance cost as compared to vehicles with other forms of fuels.
State how CFCs break ozone in the stratosphere.
Answer
The breakdown of ozone by CFCs in the stratosphere is brought about in the following way:
Describe the methods of saving the ozone layer.
Answer
Select the correct answer from the choice A, B, C given in each case.
The major pollutant released during burning of fossil fuels.
A: Carbon monoxide B: Sulphur dioxide C: Hydrogen sulphide
The green house gas which on combustion produces another green house gas.
A: Nitrous oxide B: Ozone C: Methane
The gas which in presence of U.V. light gives two atoms of the same gas.
A: Oxygen B: Ozone C: Carbon dioxide
A chemical responsible for ozone depletion.
A: Methyl acetylene B: Methyl chloride C: Methanol
A renewable source of energy which causes minimum or no pollution.
A: Fossil fuel B: L.P.G. C: Hydro power.
Answer
B: Sulphur dioxide
C: Methane
B: Ozone
B: Methyl chloride
C: Hydro power
Give balanced equations for the following conversions [one or two steps].
Answer
Sulphur trioxide to sulphuric acid
H2O + SO3 ⟶ H2SO4
Nitrogen to nitrogen dioxide in internal combustion engine
N2 + O2 ⟶ 2NO [At High Temperatures]
2NO + O2 ⟶ 2NO2
Methane to carbon dioxide
CH4 + 2O2 ⟶ CO2 + 2H2O + Δ
A molecule of ozone to two molecules of oxygen gas
O3 O2 + [O]
O3 + [O] ⟶ 2O2
Oxygen to ozone gas by photolysis
O2 [O] + [O]
O2 + [O] ⟶ O3 [ozone]
Give reasons for the following.
Natural rain water does not have a pH of 7 [i.e. neutral]
Answer
Natural rain water produced in unpolluted air is slightly acidic as CO2 present in traces in unpolluted air dissolves in rain water forming weak carbonic acid [H2CO3].
H2O + CO2 ⟶ H2CO3 [carbonic acid]
Give reasons for the following.
A catalytic converter in an internal combustion engine reduces pollution.
Answer
The reduction catalyst [Pt/Pd] of the catalytic converter separates the nitrogen atom from NO and NO2 molecules freeing oxygen in the form of O2 molecule.
2NO ⟶ N2 + O2
2NO2 ⟶ N2 + 2O2
Thus, the oxides of nitrogen which are pollutants are converted to free nitrogen by the catalytic converter thereby reducing pollution.
Give reasons for the following.
In absence of green house gases the surface temperature of the earth is maintained.
Answer
In absence of green house gases the surface temperature on earth is maintained since -
Thus, a balance is maintained between the heat energy absorbed by the earth and radiated from the earth and the surface temperature of earth is maintained.
Give reasons for the following.
The formation of ozone involves a chemical reaction called photolysis.
Answer
Highly energetic ultraviolet radiations from the sun breaks the oxygen molecule [O2] into two oxygen atoms. This chemical reaction is called photodissociation or photolysis.
The highly reactive oxygen atom [O] can then react with oxygen molecule [O2] to form ozone [O3]
O2 [O] + [O]
O2 + [O] ⟶ O3 [ozone]
Give reasons for the following.
Destruction of ozone layer is harmful for both humans and plants.
Answer
Destruction of ozone layer is harmful for humans because U.V. rays from the sun cause the following damage to humans:
U.V. rays also damage plants in the following ways:
Name or state the following:
Answer
Acid rain has adverse effects on the environment. State the effect acid rain has on the following - i.e., A: Increases or B: Decreases
Answer
The diagram represents the green house effect.
Answer